The ideal gas law and the theories based on it best model real gases when the environment is similar to the approximations upon which the theories are based. At low pressures and high temperatures, the gas molecules are sufficiently far from each other that they effectively move independently of the motions of the other molecules. At high pressures, the distance between the molecules is no longer insignificant compared to the size of the molecules. Therefore, the approximation that the molecules are infinitely small no longer holds. At low temperatures, the molecules move relatively slowly. At slower speeds, the attraction between the molecules begins to affect the motion of the molecules. If the gas is sufficiently cooled, a liquid will form.
Quantitatively, the deviations from the ideal gas law are described by the Van der Waals equation.
